Monday 14 March 2011

Structure of Diamond

The structure of diamond
The giant covalent structure of diamond
Carbon has an electronic arrangement of 2,4. In diamond, each carbon shares electrons with four other carbon atoms - forming four single bonds.

In the diagram some carbon atoms only seem to be forming two bonds (or even one bond), but that's not really the case. We are only showing a small bit of the whole structure.
This is a giant covalent structure - it continues on and on in three dimensions. It is not a molecule, because the number of atoms joined up in a real diamond is completely variable - depending on the size of the crystal.
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Note: We quoted the electronic structure of carbon as 2,4. That simple view is perfectly adequate to explain the bonding in diamond. If you are interested in a more modern view, you could read the page on bonding in methane and ethane in the organic section of this site. In the case of diamond, each carbon is bonded to 4 other carbons rather than hydrogens, but that makes no essential difference.
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How to draw the structure of diamond
Don't try to be too clever by trying to draw too much of the structure! Learn to draw the diagram given above. Do it in the following stages:

Practise until you can do a reasonable free-hand sketch in about 30 seconds.

The physical properties of diamond
Diamond
• has a very high melting point (almost 4000°C). Very strong carbon-carbon covalent bonds have to be broken throughout the structure before melting occurs.
• is very hard. This is again due to the need to break very strong covalent bonds operating in 3-dimensions.
• doesn't conduct electricity. All the electrons are held tightly between the atoms, and aren't free to move.
• is insoluble in water and organic solvents. There are no possible attractions which could occur between solvent molecules and carbon atoms which could outweigh the attractions between the covalently bound carbon atoms.

The structure of graphite
The giant covalent structure of graphite
Graphite has a layer structure which is quite difficult to draw convincingly in three dimensions. The diagram below shows the arrangement of the atoms in each layer, and the way the layers are spaced.

Notice that you can't really draw the side view of the layers to the same scale as the atoms in the layer without one or other part of the diagram being either very spread out or very squashed.
In that case, it is important to give some idea of the distances involved. The distance between the layers is about 2.5 times the distance between the atoms within each layer.
The layers, of course, extend over huge numbers of atoms - not just the few shown above.
You might argue that carbon has to form 4 bonds because of its 4 unpaired electrons, whereas in this diagram it only seems to be forming 3 bonds to the neighbouring carbons. This diagram is something of a simplification, and shows the arrangement of atoms rather than the bonding.

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